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I guess the complementary color provides a better background for the desired
color? This presents a real challenge because one must now pick the proper underlay
color.
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Underpainting with a complimentary will create a greater depth to the paint. My portraits of caucasian women have a porcelain skin quality because of painting colors between green to blue under the final fleshtones.
Picking a proper complementary color is easy if you use a color wheel. Grumbacher makes a useful and inexpensive one.
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